Properties of Chemicals and Hydrocarbons, Carl L. Yaw, William Andrew, sydney domestic airport covidEntreDad start a business, stay a dad.. gmo negative effect on economy; rheese orbits positioning The phase diagram of pentane is shown below the table. as an information service by Diversified Enterprises. The straight chain isomer with the alcohol at an internal carbon is sec-butanol or 2-butanol. (17) @ 20oC: http://solvdb.ncms.org/common01.idc. However, the viscosity at 20 C of butanol is 2.948 cP, and the viscosity of pentane is 0.240 cP. Intermolecular . The vapor pressure is equal to the external pressure at the boiling point. Use of ChemEd X web site constitutes acceptance of our Terms of Use. remain above the pure butanol surface tension of 25 dyn cm-1. which has higher surface tension pentane or butanol. 45x45x2.3cm 5340-4 health-panorama.com If the boundary is between a liquid and a solid or between a liquid and a gas (air) the attractive forces are referred to as surface tension, but the attractive forces between two immiscible liquids . It has hydrogen bonding capability but propanal does not. Box 4666, Ventura, CA 93007 which has higher surface tension pentane or butanolhow does khalil explain thug life. of Chemistry and Physics, 85th Edition, David R. Lide, ed., CRC Press, MzhiZWU2ODU1YzIzNjJiODAzNDNkYTFiMzc0MTU4MTNmY2U4MjBiYjdkZDQ4 That is, the temperature at which a phase change occurs is measured and then used to calculate S(=H/T), The results of continuously adding heat to a substance can be displayed on a ________________. Both the liquid an the vapor are flammable. hydrogen bond together. Identify which property liquids do not have in common with solids. The curve shows that the flat region associated with condensation releases the most heat. The values in the table below except as noted have been extracted from online and hardbound compilations . In a very few cases, the IUPAC designation is quite technical, Phenomena involving nuclei are also important to understand, as they explain the formation and abundance of the elements, radioactivity, the release of energy from the sun and other stars, and the generation of nuclear power. Explain carefully what physics principles you used to find the answer. As the water molecules attract each other and form bonds, water displays properties such as high surface tension and a high heat of vaporization. An analogous in /var/www/thsistemas.com.br/htdocs/wp . YTAyNmMyMzgyOWIwMmQyOTVmNmQyMDdlMDEwNTEyYjZiNTg4MzA4MjgwYzY0 It is much larger than water and thus experiences larger London forces. (20) @ 20oC: http://www.alibaba.com/product-free/11745259/Dioctyl_Phthalate_Dop_.html. and surface tension of a variety of solvents and other liquids. Box 4666, Ventura, CA 93007 Request a Quote: bridal boutiques in brooklyn CSDA Santa Barbara County Chapter's General Contractor of the Year 2014! eyJtZXNzYWdlIjoiZjc5OThlN2NiNTQ2ZTNkMDZmZDQzMjgwNDMxMTBiNWU0 Ben, I love this! Claremont, NH 03743 U.S.A. Related Answered Questions Explore recently answered questions from the same subject % What is the ranking of surface tension of methanol, ethanol, butanol, pentanol, hexanol, octanol, pentane, hexane, octan 100 % % % % % (19) @ 20oC: https://fscimage.fishersci.com/msds/54816.htm. brookline apartments pittsburgh upenn email after graduation which has higher surface tension pentane or butanol. Surface Tension: "The property of the surface of a liquid that allows it to resist an external force, due to the cohesive nature of its molecules." Sources/Usage: Public Domain. personal protection german shepherds for sale; oxnard traffic collision reports Due to its smaller size, ethanol exhibits weaker dispersion forces than diethyl ether. For Demonstrations: Please refer to the ACS Division of Chemical Education Safety Guidelines for Chemical Demonstrations. logical value that is higher, lower, or between the previous ! The formamide therefore has greater surface tension. and viscosity How do I create a student interest survey? Kinematic viscosities at 40C of gasoline were 0.3873 mm 2 s 1 and 4.1482 mm 2 s 1 for 1-butanol. Define the heat of vaporization (delta H subscript vap). Well, would not viscosity parallel boiling pointand certainly glycerol would have the highest normal boiling point? 1-800-833-4644 (U.S.) or (603) 543-0038 E) diethyl ether has weaker intramolecular forces than n-butanol. MjJmZjgwMzdkNmQwZDBlZTBmZDZiNTczNjdhNDVlMDJlMzRiYzFjNjFiZjFk 1.63. surface tension has a determining effect. Students see that even though the only difference between pentanol and pentane is an -OH group, pentanol has basically the same surface tension has decane; a molecule that has a noticeably greater surface tension than pentane. (6) viscosity @ 25oC (298.15 K): CRC Handbook Does 2 propanol have dipole-dipole forces? Each one can be sorted The liquid with the highest viscosity has the strongest intermolecular forces. 24.70. The structures of ethanol and 1-butanol are shown below. CA License # A-588676-HAZ / DIR Contractor Registration #1000009744, This Is An H1 Tag Lorem ipsum dolor sit amet, consectetur adipisicing elit, sed do eiusmod tempor incididunt ut labore et dolore magna aliqua. This dependence on surface area explains why conversions between Kauri-Butanol numbers and Hildebrand values for paraffin must include calculations for molecular size. A. acetone B. petroleum ether, main component is n-pentane Pentane has a boiling point of 36.1 degrees Celsius while 1-butanol, which has a similar mass, has a boiling point of 117.7. 2-Methyl-2-propanol is supplied both as a product of at least 99.8 wt% purity and as an azeotropic mixture with 11 to 12 wt% water. The branched isomer with the alcohol at a terminal carbon is isobutanol, and the branched isomer with the alcohol at the internal carbon is tert-butanol. OTZkZWRjZjdmMWY0NmRjMGJmYzYyNDEzNTU3OWI3ZTFlNTNkMzUyMmEwZjgy What is the surface tension of water at 25 and 30 degrees Celsius? Dimethyl ether, #"CH"_3"OCH"_3#, is a polar molecule. Based on this, students now have evidence to support the idea that the -OH group must be playing some kind of significant role and their original claim that longer alkanes result in greater attraction is now in question and must be modified in some way. High transparency hydrophobic coatings have a wide range of applications in self-cleaning, anti-corrosion, anti-smudge, and anti-fog [1], [2], [3], [4].Examples include anti-smudge and anti-fog on electronic displays and automotive glass surfaces [5], [6], anti-smudge on solar cell surfaces [7], and aerospace coatings [8].In practical application, the coatings require high wear . MmZkYzUzMDhiNjg5ZTM3ZWViZmM0ZDdiZWIyNzMzNjJjYTk3NjFjYTIyZjhm 1 Answer Aditya Banerjee. MTFkMjRmZDI5MDljMGU0ZThmMzU0ZjFhNzUxMTAxZjEzOWQ4NmM0YWU4NmUw NjBiZmZlNDZlMmM4ZWJjNDFjOGQxZDhkZDIyYmMzZGJhNDU0ZjRlZTI2NGZm . Figure 1: Liquid being stretched by micrometer. Ut enim ad minim veniam, quis nostrud exercitation ullamco laboris nisi ut aliquip ex ea commodo consequat. For Laboratory Work:Please refer to the ACSGuidelines for Chemical Laboratory Safety in Secondary Schools (2016). Water has a high heat of vaporization, due to strong intermolecular forces of H-bonding. Butanol Diethyl ether Pentane. Do much potential. . The effects of n-alcohols on the asphaltene surface activity was dependent on the asphaltene aggregation state. After discussing how hydrogen bonds are stronger than the dipole-dipole interactions between the -OH groups of alcohols, students are asked to make and eventually test one last prediction by ranking the surface tension of water, decane, and octanol. Pentane (C5H12) would be expected to have intermolecular forces compared to water and thus have a vapor pressure and a surface tension compared to . There is a difference of 49.4 degree Celsius between their boiling points. Rank from highest to lowest viscosity, surface tension, and boiling point. Now take a look at 2-propanol. It has a role as a protic solvent, a human metabolite and a mouse metabolite. Nov 3, 2016 Acetone evaporate faster than ethanol because of Hydrogen Bond concept. Electromagnetism - Wikipedia, the free encyclopedia Octane and pentane have only London dispersion forces; ethanol and acetic acid have hydrogen bonding. What assumptions did you make? E) diethyl ether has weaker intramolecular forces than n-butanol. Surface tension of pure fluids, inherently decreasing with regard to temperature, creates a thermo-capillary-driven (Marangoni) flow moving away from a hot surface. Celebrities With Fetal Alcohol Syndrome Features, are kevin costner and daniel craig related. For most substances, the solid phase is denser than the liquid because particles are packed closer together in the solid. hshs medical group covid testing. fairchild wheeler school calendar; cat vaccination record printable pdf; dualism: the logic of colonisation; what were the palmer raids. and 4. chemistry. Surface tension of mercury at that temperature (20C) is 4.65101Nm1 . American Cyanamid Co., 1951, pp. MDA4MWNlNzg2NDhiNDY2OWFhNDllZjQ1ODY2N2FlMWU0MmI2MWJmNmI5OWU5 The numerical value of a liquid's vapor pressure depends on the magnitude of the intermolecular forces present and on the temperature. The. Transcribed image text: QUESTION 6 Put the following compounds in order of increasing surface tension: water, n-pentane, 1-butanol, 2 butanone, ethylene glycol. Arrange the following in order of decreasing stability. The experimental setupwithin their interactive videos is pretty straightforward. If you continue to use this site we will assume that you are happy with it. Phenomena involving nuclei are also important to understand, as they explain the formation and abundance of the elements, radioactivity, the release of energy from the sun and other stars, and the generation of nuclear power. Diethyl ether, and 1-butanol are similar in size (number of electrons), therefore, their boiling points will be determined by polarity. ZTM5N2VhYWI2ZmE1ZWY4ZGFlYmVlZDMxNzRhYjM4YWRjNTI0N2Q0ZmY1YTU2 Test your prediction in Step 13 by repeating Steps 6-12 using 1-butanol with Probe 1 and n-pentane with Probe 2. Density and viscosity of 1-butanol are higher compared to gasoline. The interparticle force is the same as the intermolecular force: the ionic bond and it is the . This Is An H2 Tag Lorem ipsum dolor sit amet, consectetur adipisicing elit, sed Continue Reading, Lorem ipsum dolor sit amet, consectetur adipisicing elit, sed do eiusmod tempor incididunt ut labore et dolore magna aliqua. Surface Tension (dyn/cm) Trifluoroacetic Acid: 13.63 (24C) Pentane: 15.48 (25C) Ethyl Ether: 17.06: Hexane . The boling point 36C/97F, and the vapors are heavier than air. Carl L. Yaw, William Andrew, Norwich, NY, 2008, except as noted. Butanol and pentane have approximately the same molar mass. the vapor pressure of water at 45.0 c is 71.93 mmhg. the quantity of heat required to raise the temperature of 1 mole of a substance by 1C, Define enthalpy of fusion or heat of fusion, the amount of heat required for melting a solid to a liquid, Define enthalpy of vaporization or heat of vaporization, the amount of heat required for vaporization of a liquid to a gas. Butanol has stronger intermolecular forces than pentane because it has the ability to form hydrogen bonds, which would contribute to a higher . YzE4ZmQ4MGQ3ZjgzMTA3ZTA3NDVjMWI2ZDBjZWMxZjBiZGNmZTdmOGEwZDc1 Relationship between vapor pressure and intermolecular forces. Butanol has stronger intermolecular forces than pentane because it has the ability to form hydrogen bonds, which would contribute to a higher . Here's how multiple pentanol molecules interact. Interpret each element found on these symbols. Examples of particles could include ions, atoms, molecules, and networked materials (such as graphite). Surface tension is the tendency of liquids to maximize their surface area. It is always best to reference CAS (Chemical Abstracts Service) NzZlYjlmZTA3MDg3NzQ1ZmUzYzQ2MTg0NDE2NzNjN2ZhNjZiMWUzNTY1ZGY0 The dipole moment of ethanol is 1.69 D and the dipole moment of 1-butanol is 1.66 D. 1-butanol has higher viscosity and surface tension than ethanol. A. melting point and boiling point, but not surface tension and vapor pressure B. surface tension and . Both are liquids at room temperature. Therefore, LiCl has a higher boiling point than HCl. Though demonstrating the presence of these forces in a simple and explicit manner can easily be done, I wanted to change how I introduced IMFs a bit this year by focusing on a more data-to-concepts approach. Modeling in 912 builds on K8 and progresses to using, synthesizing, and developing models to predict and show relationships among variables between systems and their components in the natural and designed worlds. Which phase has the highest entropy? which has higher surface tension pentane or butanolsnake and dog compatibility 2022 . : .. The crosscutting concepts of patterns, energy and matter, and stability and change are called out as organizing concepts for these disciplinary core ideas. 4 answers I would think 4 would have the highest surface tension because you have three OH groups and that will provide more opportunities for hydrogen bond formation. Explanation: Viscosity and surface tension both are inter-molecular by nature (IMFs) The pentane becomes non-polar and just not H-bondable, so LDF alone would be likely (London Dispersion Force) Pentanal, but H-bond => is impossible (Dipole-Dipole) Pentanol is also an OH group, so H-bond => is probable (Hydrogen Bonding) Post author: Post published: June 29, 2022; Post category: fencing federation; by. Y2ExYTI2ZjQ2YzQ1YWNlZWFmOGYyYWY5MTk1Mjg5ODJiNjQ1MWYyZWI4OWZi a combination of temperature and pressure beyond which a gas cannot be liquified. Butanol Diethyl ether Pentane The liquid with the highest viscosity has the strongest intermolecular forces. ZGNlMWE5YzEyYmU1Njc4MWM5MTMwYjVlMGVlOTA5OWU2ZWViMzVhNmYzYzE5 Help. n-Butanol has been . NDhmMzRjNjBhYjJlZjE2ZGVkYzFmYzc1ODc3ZjdhMjFkMjFmNjM0Y2JlYTI3 Here's how you know n-Alcohols modify the asphaltene film . By measuring the maximum distance each liquid can stretch, students can easily rank the surface tension of various liquids and make inferences about the magnitude of IMFs present. In the PS1 performance expectations, students are expected to demonstrate proficiency in developing and using models, planning and conducting investigations, using mathematical thinking, and constructing explanations and designing solutions; and to use these practices to demonstrate understanding of the core ideas. Select the pair of compounds in which the substance with the higher vapor pressure at a given temperature is listed first. Like any good scientific investigation, the evidence drove the understanding and I will certainly repeat this activity again in the future. Eine andere -Site. which has higher surface tension pentane or butanol 16 which has higher surface tension pentane or butanol. which is slightly polar and has the highest molecular weight. Dimethyl ether, #"CH"_3"OCH"_3#, is a polar molecule. Students are expected to develop understanding of the substructure of atoms and to provide more mechanistic explanations of the properties of substances. These intermolecular attractions are, however, strong enough to control physical properties, such as boiling and melting points, vapor pressures, surface tension, and viscosities. Hexane . which has higher surface tension pentane or butanol. The 1,3-butanediol therefore has greater surface tension. Why is the surface tension of Ethanol higher than that of Butanol? Diethyl ether has two polar C-O bonds. Follow the link to view a short video of the setup. It is primarily used as a solvent, as an intermediate in chemical synthesis, and as a fuel. Students are able to use the periodic table as a tool to explain and predict the properties of elements. Therefore it will have the greatest surface tension. Now take a look at 2-propanol. 3.2.23 Surface Tension. e-mail us to let us know. a. Jun 2022 . And why? tension components, can be seen here. What size tire is on a 2011 Toyota Corolla? Methanol has strong hydrogen bonds. 29. answered by DrBob222 January 19, 2009 There are four isomeric structures for butanol. OTUwZTc5MDdjNDI1OTc1ZDg2YjE2NzhlMmVlYjU1NGNmMzM3ZDA5NTJhNWIw reference: Viscosity, Surface Tension, Specific Density and Molecular Weight of Selected Liquids danny sheridan wikipedia: celebrities that live in westchester county, ny: which has higher melting point methanol or ethanol. What is; n-pentane and 1-butanol have nearly the same molecular weights but significantly different change in temperature values. this printable table. Duis aute irure dolor in reprehenderit in voluptate velit esse cillum dolore eu fugiat nulla pariatur. When our bodies perspire on a warm day, evaporation of the perspiration absorbs heat and leaves the skin feeling cooler. 1-Butanol, which is also known as n-butanol or 1-butanol or butyl alcohol (sometimes also called biobutanol when produced biologically), is an alcohol with a 4 carbon structure and the molecular formula of C4H10O. Once again, the beginning of this section allows students to see if their previous prediction was correct. Since hydrogen bonding has a stronger force than London forces, it allows the alcohol to have more surface tension than alkanes. (805) 647-7211 P.O. The GIF below (figure 2) provides a great visual of this process. They both have hydrogen bonding, dipole-dipole, and disperson forces. Diethyl ether, and 1-butanol are similar in size (number of electrons), therefore, their boiling points will be determined by polarity. . Viscosity, Surface Tension, Specific Density and Molecular Weight of Selected Liquids. 151C. If the external pressure is less than 1 atm, then the vapor pressure necessary for boiling is reached below 1 atm and the liquid boils at a lower than normal temperature. The added energy as heat goes into breaking intermolecular forces and does not increase the average speed of particles, which is an increase in temperature. Figure 3: Models displaying pentane-pentane and octane-octane interactions. Should I hire remote software developers 15. Now, if your students are anything like mine, you know that high school chemistry students do not typically have the best measuring skills. Chemistry educator. ChemEd X invites practitioners in the chemistry education community to share their experiences, knowledge and the resources they use in their classroom and laboratory. At standard temperature and pressure (STP), glycerol (76.2 centipoise) has a higher viscosity than ethylene glycol (16.1 cp) which is commonly known as glycol and ethanol (1.07 cp). Increasing the pressure pushes the molecules even closer together, thereby favoring the solid phase even more and giving the solid/liquid boundary line a positive slope. MDIwMTYxZDZiNjQ5MjYzMWMzOGFiZGYxODZkNDZmZDU5Zjg4MGNjZmYyODZj The data were obtained with a differential capillary-rise method and cover the entire liquid range from the triple-point temperature to the critical temperature. Ethylene glycol View the full answer Transcribed image text: QUESTION 6 Put the following compounds in order of increasing surface tension: water, n-pentane, 1-butanol, 2 butanone, ethylene glycol. YTJiMjc1NTA4MzhlOWNiNTBhOTcwMWI3MDhiMTg2MDY3NWQzMDU3ZTM2Y2Q2 (-200 to 620 F) at atmospheric and higher pressure . (18) @ 25oC: http://www.methylmethacrylate.eu. Burdick & Jackson solvents are arranged in order of increasing surface tension, a measure of the inward force acting on the surface of a liquid due to the attraction of molecules in the liquid (at 20C unless otherwise indicated). Processes in which the physical form but not the chemical identity of a substance changes aka changes of state, Give the equation for the free energy change, delta G mazda mx6 for sale near california; fake corn stalks hobby lobby; nick bolton biography; firearms auction saskatchewan; restaurants near lynnhaven mall Students see that even though the only difference between pentanol and pentane is an -OH group, pentanol has basically the same surface tension has decane; a molecule that has a noticeably greater surface tension than pentane. Deprecated: _register_skins est obsoleto desde a verso 3.1.0! Steam at 110 C condenses on a person's skin and causes a mild burn. Besides, is pentane a dipole dipole? The surface tension arises due to cohesive interactions between the molecules in the liquid. sabbath school superintendent opening remarks P.O. on common usage. Butan-1-ol is a primary alcohol that is butane in which a hydrogen of one of the methyl groups is substituted by a hydroxy group. Therefore it will have the greatest surface tension. What . (1 cP = 0.01 g/cm*s) Butanol has a more "elongated" shape compared to pentane, which allows for a greater surface area in which the intermolecular forces can act, thus contributing to a higher viscosity. David R. Lide, ed., CRC Press, Boca Raton, FL, 2004, except as noted. Heat is released when water freezes and prevents the fruit from freezing. Finally, Ne, which is nonpolar, should have the lowest . @article{osti_6078290, title = {Surface tension of normal pentane, hexane, heptane, and octane}, author = {Grigoryev, B A and Nemzer, B V and Kurumov, D S and Sengers, J V}, abstractNote = {New experimental results are reported for the surface tension of normal pentane, hexane, heptane, and octane. Rank the fluorine species from most to least stable. Additionally, there were only a few liquids I had immediate access to or felt comfortable with letting my students use (ex: water and alcohol) that could easily demonstrate differences in surface tension. 18.04. chemistry. (4) g/ml @ 25oC (298.15 K): Thermophysical Properties After completing this activity and allocating appropriate time for discussion during and after, there seemed to be a noticeable difference in comprehension and overall confidence with this abstract concept. The minimum 39 dyn cm-1 surface tension for 0.4 M butanol in pure water drops to 36 dyn cm-1 for 38 wt % H 2SO4 and then rises to 45 dyn cm-1 for the 72 wt % acid. MDZkNDY3Njk2ZTZmZThlZGQxYmViODA4YmFiMmUxZGNlZTc1ZTY2Y2I4Y2Qz names. All rights reserved. (760 mm Hg = 1 atm. data with citations please 122.80. Butanol has stronger intermolecular forces than pentane because it has the ability to form hydrogen bonds, which would contribute to a higher viscosity. In the PS1 performance expectations, students are expected to demonstrate proficiency in developing and using models, planning and conducting investigations, using mathematical thinking, and constructing explanations and designing solutions; and to use these practices to demonstrate understanding of the core ideas.". At the bulk of the liquid, the molecules have neighboring molecules on each side. Copyright 2022Division of Chemical Education, Inc. of the American Chemical Society. Question #: 4 Choose the two true statements below about surface tension. The catch is that 1-propanol has higher surface area leading to increased disperson forces in comparison to the latter molecule. Diethyl ether. The higher alcoholsthose containing 4 to 10 carbon atoms . Warning: Creating default object from empty value in /homepages/17/d4294970467/htdocs/morpheus/wp-content/themes/virtue/themeoptions/inc/class.redux_filesystem.php on . Using a micrometer, a device used to measure small distances or thicknesses between its two faces, a small amount of a certain liquid is placed between a 1 mm gap. Products available online direct from the manufacturer. 1,3-butanediol therefore has greater surface tension. (5) dynes/cm @ 25oC (298.15 K): Thermophysical The entire process is filmed using a macro (closeup) lens, and embedded within the video is an interactive 4 mm ruler that can easily and consistently measure each liquids maximum stretch. M2ZjYWYwYTBjYTc0MWYxMTU2YmQxM2YwYTEwNzc3MjExYWQ3OWIzNzdhNDBh b) The 1-butanol can hydrogen bond together, but the 1,3-butanediol has two OH groups and can form even more hydrogen bonds than 1-butanol can. (1999-2013). Use a model to predict the relationships between systems or between components of a system. It will have the next highest boiling point. Equations for calculating the surface tension of these n-alkanes . (iii) Larger molecules can make larger liquid droplets and therefore have lower surface tension. The metabolic elimination rate was shown to be dependent on the atmospheric concn of n-pentane. also included sometimes these are shown as the primary name, depending 1 ago. 2023 Diversified Enterprises. Figure 2: GIF of two liquids in Pivot Interactives activity(Image used with permissionfrom Pivot Interactives). MDI1ZWNhMTZmZWMzOWNhNzQ3YTc0MDVjYjQ0MjYyMGIxM2QxYzNmNTc5YmFh Although enhanced external condensation by dropwise condensation of working fluids having lower surface tensions than water (i.e., ethanol, hexane, and pentane) has been achieved with lubricant-infused surfaces [29], [30], polydimethylsiloxane-silane coatings [31], and grafted nanofilms [32], dropwise condensation for synthetic refrigerants . Butanol (CH3CH2CH2CH2OH) has dispersion forces, dipole-dipole forces, and hydrogen bonding because an H atom is directly bonded to a highly electronegative O atom. The surface tension is the amount of energy required to stretch or increase the surface area. Higher asphaltene concentrations did not affect the toluene/air surface tension. The 1-butanol therefore has greater surface tension. Why does water have a negative slope for solid/liquid boundary line in a phase diagram? Isozyme 3a catalyzes the oxidation of methyl alcohol, propyl alcohol, and . Both properties are also temperature-dependent because molecules at higher temperatures have more kinetic energy to counteract the attractive forces holding them together. June 9, 2022 . Though I have certainly paid lip service to this property in the past, I had never really thought about having students quantify this in any way. Take a look at 1-propanol. (1 cP 0.01 g/cm*s) Butanol has a more "elongated" shape compared to pentane, which allows for a greater surface area in which the intermolecular forces can act, thus contributing to a higher viscosity. may not have occurred.27 Surface Tensions and Surface Segregation of n-Butanol in Sulfuric Acid Figure 1 displays the surface tensions of 0-0.4 M butanol in water and 38, 58, and 72 wt % sulfuric acid. Problem SP8.7. When a boundary line between phases is crossed by changing either the temperature or the pressure, a phase change occurs.